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Why does ice float on water?

 

Why does ice float on water? (Don’t say that it is common sense, please!) According to my knowledge, solids are usually heavier than liquids. Why is water so special?
 

Kaku (Dec 2000)

 

Answer:
The reason why ice is lighter than water is that a certain mass of ice occupies more space than the same mass of water. This is related to “hydrogen bonding”.
 
 
Hydrogen bonding

A water molecule is composed of two hydrogen atoms (H) and one oxygen atom (O). The atoms of hydrogen and oxygen are bound by sharing their electrons with one another. This bond is called a “covalent bond”. 

  
However, since oxygen atoms pull electrons more strongly than hydrogen atoms, the oxygen atom in a water molecule has a slightly negative charge and the hydrogen atoms have a slightly positive charge. So adjacent water molecules are attracted to one another through the slightly negatively charged oxygen atoms and the slightly positively charged hydrogen atoms. This interaction is called “hydrogen bonding”. Hydrogen bonding is much weaker than covalent bonding, however, this type of bonding has a large total effect because there are so many hydrogen bonds.
  
Structure of ice and water
Ice has a diamond structure due to the hydrogen bonding. Water does not have such an orderly structure, but water molecules are squeezed close to one another because of the hydrogen bonding.

  
Take a look at the actual structures of ice and water (see pictures below, pictures are kindly donated by MathMol). The red balls represent oxygen atoms, and the while balls represent hydrogen atoms.
  

Ice

Water

 
There is more space in ice than in water! This is the reason why ice is lighter than water. Therefore, ice can float on water.
  
 
Acknowledgement
MathMol
There is a more detailed explanation about the characteristics of water in this website. We referred to part of this website when we created this article.

 
 

This article is translated by Chemistryquestion.com from the original article in Chemistryquestion.jp.  Please let us know if you find any errors.

 
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